The White House has announced that US President would join Narendra Modi at the mega Houston rally, which would be attended by more than 50,000 Indian Americans, on September 22.
Mertens converted a penalty on 82 minutes and Llorente added a second in stoppage time as Napoli gained a measure of revenge for last season's 1-0 defeat at Anfield that denied the Italians a spot in the knockout rounds.
Even with Messi on the field it was the Germans who were more dangerous after captain Marco Reus' 57th minute penalty was saved by Marc Andre ter Stegen.
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